Hydrogen adsorption on metal-organic framework MOF-177
نویسندگان
چکیده
منابع مشابه
Hydrogen adsorption in an interpenetrated dynamic metal-organic framework.
A metal-organic framework Zn(NDC)(4,4'-Bpe)(0.5).xG [NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bpe = 4,4'-trans-bis(4-pyridyl)ethylene; G = guest molecules] has been synthesized, structurally characterized, and rationalized to be a two-interpenetrated elongated primitive cubic net. Powder X-ray diffraction and adsorption studies reveal the dynamic feature of the framework, which can take up hydr...
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Metal-organic framework-177 (MOF-177) is one of the most porous materials whose structure is composed of octahedral Zn4O(-COO)6 and triangular 1,3,5-benzenetribenzoate (BTB) units to make a three-dimensional extended network based on the qom topology. This topology violates a long-standing thesis where highly symmetric building units are expected to yield highly symmetric networks. In the case ...
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ژورنال
عنوان ژورنال: Tsinghua Science and Technology
سال: 2010
ISSN: 1007-0214
DOI: 10.1016/s1007-0214(10)70075-4